RobertRyanHolmesMD

PubMed

• Biologically relevant phosphoranes: synthesis and structural characterization of glucofuranose-derived phosphoranes with penta- and hexacoordination at phosphorus.
  Timosheva, N.V., Chandrasekaran, A., Holmes, R.R.> ;Inorg Chem. 2006 Dec 25
• Biologically relevant phosphoranes: structural characterization of glucofuranose- and xylofuranose-based phosphoranes.
  Timosheva, N.V., Chandrasekaran, A., Holmes, R.R.> ;Inorg Chem. 2006 Apr 3
• Biologically relevant phosphoranes: structural characterization of a nucleotidyl phosphorane.
  Timosheva, N.V., Chandrasekaran, A., Holmes, R.R.> ;J Am Chem Soc. 2005 Sep 14
• Phosphorus-nitrogen donor interaction leading to atrane formation in phosphate and oxyphosphorane compositions. Implications for phosphoryl transfer enzymes(1).
  Timosheva, N.V., Chandrasekaran, A., Holmes, R.R.> ;Inorg Chem. 2004 Nov 15
• Phosphoryl transfer enzymes and hypervalent phosphorus chemistry.
  Holmes, R.R.> ;Acc Chem Res. 2004 Oct
• Influence of hydrogen bonding in competition with lattice interactions on carbonyl coordination at phosphorus. Implications for phosphoryl transfer activated states.
  Chandrasekaran, A., Timosheva, N.V., Day, R.O., Holmes, R.R.> ;Inorg Chem. 2003 May 19
• Pseudoheptacoordination and pseudohexacoordination in tris(2-N,N-dimethylbenzylamino)phosphane.
  Chandrasekaran, A., Timosheva, N.V., Day, R.O., Holmes, R.R.> ;Inorg Chem. 2002 Oct 7
• Conversion of tricoordinate to hexacoordinate phosphorus. Formation of a phosphorane-phosphatrane system.
  Timosheva, N.V., Chandrasekaran, A., Day, R.O., Holmes, R.R.> ;J Am Chem Soc. 2002 Jun 19
• P-O donor action from carboxylate anions with phosphorus in the presence of hydrogen bonding. A model for phosphoryl-transfer enzymes.
  Chandrasekaran, A., Day, R.O., Holmes, R.R.> ;Inorg Chem. 2002 Mar 25
• Coordination of carbonyl and carboxyl oxygen atoms with phosphorus in the presence of hydrogen bonding. P-O donor action.
  Chandrasekaran A, Day RO, Holmes RR> ;Inorg Chem. 2001-11-19
• Synthesis and structure of cyclic phosphate, phosphoramidate, phosphonates, and phosphonium salts. Phosphatrane formation.
  Chandrasekaran A, Day RO, Holmes RR> ;Inorg Chem. 2000-12-11
• Crystal structures of tris(8-dimethylaminonaphthyl)phosphane and its hydrochloride salt. The first seven-coordinate phosphorus compound.
  Chandrasekaran A, Timosheva NV, Day RO, Holmes RR> ;Inorg Chem. 2000-04-03
• Chloro- and Fluoro-Substituted Phosphites, Phosphates, and Phosphoranes Exhibiting Sulfur and Oxygen Coordination(1).
  Chandrasekaran, A., Sood, P., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1999 Jul 12
• Cyclic Three-, Four-, Five-, and Six-Coordinate Nitrogen-Containing Phosphorus Compounds Varying in Ring Size from Five- to Ten-Membered. P-N Donor Action(1).
  Timosheva, N.V., Chandrasekaran, A., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1998 Sep 21
• Increased Coordination via Sulfur Donor Action in Cyclic Pentaoxyphosphoranes and the Parent Cyclic Phosphite. Influence of Pentafluorophenoxy Ligands(1).
  Sood, P., Chandrasekaran, A., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1998 Jul 27
• Molecular Structures of Three-, Four-, and Five-Coordinate Phosphorus Compounds Containing Salicylate Ligands(1).
  Timosheva, N.V., Chandrasekaran, A., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1998 Jul 27
• Structure-Reactivity Relationships for Associative Displacement Reactions of Penta- and Hexacoordinate Cyclic Oxyphosphoranes with Catechols(1)(,)(2).
  Chandrasekaran, A., Sood, P., Holmes, R.R.> ;Inorg Chem. 1998 Feb 9
• Conformational Preference and Donor Atom Interaction Leading to Hexacoordination vs Pentacoordination in Bicyclic Tetraoxyphosphoranes(1).
  Sherlock, D.J., Chandrasekaran, A., Prakasha, T.K., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1998 Jan 12
• Hexacoordination via Sulfur Donor Action in Bicyclic Pentaoxyphosphoranes(1).
  Sood, P., Chandrasekaran, A., Prakasha, T.K., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1997 Dec 3
• Axial Site Occupancy by the Least Electronegative Ligands in Trigonal Bipyramidal Tetraoxyphosphoranes(1).
  Timosheva, N.V., Chandrasekaran, A., Prakasha, T.K., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1996 Oct 23
• Synthesis and Molecular Structures of Pyridine-Containing Large-Membered Cyclic Bis(alkoxy)silanes(1).
  Prakasha, T.K., Chandrasekaran, A., Day, R.O., Holmes, R.R.> ;Inorg Chem. 1996 Jul 17
• Comparison of Phosphorus and Silicon: Hypervalency, Stereochemistry, and Reactivity.
  Holmes, R.R.> ;Chem Rev. 1996 May 9
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